含甲醛毒性废水电_Fenton试剂氧化技术研究.docxVIP

第 24 卷第 6 期 2003 年 11 月 环 境 科 学 ENV IRONMEN TAL SCIENCE Vol. 24 ,No. 6 Nov. ,2003 含甲醛毒性废水电2Fenton 试剂氧化技术研究 胡成生 ,王刚 ,吴超飞 ,李平 ,韦朝海 3 (华南理工大学环境科学研究所 ,广州 510640 , E2mail :cechwei @scut. edu. cn) 摘要 :研究了以活性炭粒子为填充电极的填充床式电2Fenton 反应装置处理自配甲醛毒性有机废水时各影响因子 的作用机制 ,通过正交实验和单因素实验确定了各影响因子的最佳操作条件为 :反应时间 90min ,反应体系 p H 值 315 ,涂膜炭填充比例 40 % ,电压 25V , Fe2 + 浓度 300mg/ L ,反应温度 30 ℃～40 ℃. 结合氧化产物的紫外光谱分 析 ,提出甲醛电2Fenton 氧化反应机理. 利用电2Fenton 试剂氧化法对实际洗胶废水进行连续处理 ,甲醛及 CODCr 的去除率分别在 90 %及 30 %左右 ,运行费用较 Fenton 试剂法降低 4213 %. 关键词 :含甲醛废水 ;电2Fenton 反应 ;三维填充电极 ;催化氧化 中图分类号 : X783 文献标识码 :A 文章编号 :025023301 (2003) 0620620106 Oxidation Treatment of Formal dehyde2conta ining Waste water by Electro2 Fenton Method Hu Chengsheng , Wang Gang , Wu Chaofei , Li Ping , Wei Chaohai( Environmental Science Institute , Sout h China University of Technology , Guangzhou 510640 , China) Abstract :The mechanisms of affecting factors in treating formaldehyde2containing organic wastewater by electro2Fenton reactor which had granular carbon as the filled electrode were investigated. The optimal operating conditions determined by orthogonal experiments and individual factor experiments were as following : 90min , 25V , 30 ℃～40 ℃, insulating carbon content 40 % , Fe2 + concentration 300mg/ L at p H 315. Formaldehyde degradation mechanisms were proposed after analyzing the oxidation products with UV absorbance spectrum. Experiment of treating the actual wastewater us2 ing this method were also performed. The removal rates of formaldehyde and CODCr were about 90 % , 30 % , respective2 ly. In addition , the operating cost was 4213 % less than that of treatment by Fenton method. Keywords :formaldehyde2containing wastewater ; electro2fenton reaction ; three2dimensional filled electrode ; catalytic ox2 idation Fenton 试剂在有毒 、难降解有机废水处理 方面具有明显的优势而倍受人们的关注 ,光 、电 等协同作用下的 Fenton 试剂能够更高效地产 生·O H[ 1 ,2 ] ,使反应持续稳定地进行. 首先研制 以活性炭粒子为填充电极和以涂膜活性炭为绝 缘物构成的填充床形式复极性三维电极反应 器 ;然后在电场作用下 ,活性炭填充电极通过表 面催化作用将吸附