聚芳基醚13恶二唑类聚合物的磺化及表征.PDFVIP

第26 卷第5 期 高 校 化 学 工 程 学 报 No.5 Vol.26 2012 年10 月 Journal of Chemical Engineering of Chinese Universities Oct. 2012 文章编号：1003-9015(2012)05-0870-07 聚(芳基醚1,3,4-噁二唑)类聚合物的磺化及表征 周万立, 杨 潇, 马莹莹, 叶光斗, 徐建军 (四川大学 高分子科学与工程学院 高分子材料工程国家重点实验室, 四川 成都 610065) 摘 要：为了探索影响芳香族聚噁二唑的磺化反应的因素，分别以发烟硫酸和氯磺酸为磺化试剂对几种含醚键聚芳噁 二唑(PEODs)进行磺化，研究了以氯磺酸为磺化试剂时磺化反应时间、用量对磺化反应的影响，并分析了PEODs 用于 质子交换膜的潜在应用。磺化产物的结构与性能通过傅里叶红外(FT-IR)、氢谱(1H-NMR) 、离子交换当量、热重分析(TGA) 和溶解性等测试进行了表征。结果表明：发烟硫酸磺化产物磺化度不可控制，磺化度较氯磺酸的磺化产物高；采用氯 磺酸磺化时，磺化时间对磺化反应没有影响，氯磺酸用量仅对侧苯基双酚A 型聚噁二唑有影响；邻叔丁基型聚噁二唑 的氯磺酸磺化产物有用于质子交换膜的潜力。 关键词：含醚键聚芳噁二唑；磺化；发烟硫酸；氯磺酸；质子交换膜 中图分类号：TQ203.9 文献标识码：A Synthesis and Characterization of Sulfonated Poly(arylene ether1,3,4-oxadiazole)s ZHOU Wan-li, YANG Xiao, MA Ying-ying , YE Guang-dou , XU Jian-jun (College of Polymer Science Engineering, State Key Laboratory of Polymeric Materials Engineering, Sichuan University, Chengdu 610065, China) Abstract: In order to explore the factors that affect the sulfonation reaction of the aromatic polyoxadiazoles, a series of poly(arylene ether 1,3,4-oxadiazole)s (PEODs) were sulfonated by oleum and chlorosulfuric acid, respectively. The influence of the reaction time and the amount of chlorosulfuric acid on the sulfonation were investigated, and the potential feasibility of the PEODs used as proton conducting membranes was explored. The structure and properties of the sulfonated products were characterized by FT-IR, 1H-NMR, ion-exchange equivalent, TGA and solubility tests, respectively. The results show that the sulfonation degrees of the products sulfonated by oleum are uncontrollable and higher than