在双碱法烟气如脱硫系统的亚硫酸盐氧化的抑制作用【最新】.docVIP

Available online at JOURNAL OF ENVIRONMENTAL SCIENCES ISSN 1001-0742 ScienceDirect Journal of Environmental Sciences 19(2007) 226—231 CN 11-2629/X ww’v.jese.ac.dn Oxidation inhibition of sulfite in dual alkali flue gas desulfurization system MO Jian-song’, WU Zhong-biao”, CHENG Chang-jie2, GUAN Bao-hong1, ZHAO Wei-rong’ 1. Department of Environmental Engineering, Zhejiang University. Hangzhou 310027, China. E-mail: wuzb@ 2. Zhejiang 7ianlan Desulfurization and Dust-Removal Co., Ltd., Ilangzhou 310012, China Received 18 January 2006; revised 29 Match; accepted 21 April 2006 Abstract A laboratory-scale well-mixed thermostatic reactor with continuously blasting air was used to investigate the oxidation inhibition of sulfite in dual alkali flue gas desulfurization (FGD) system. The effects of operating parameters such as pH value and catalyst concentration on the oxidation were studied. Sodium thiosulfate was used in the system, and was found that it significantly inhabited the sulfite oxidation. In the absence of catalyst, sodium thiosulfate at 12.67 mmol/L had an inisibition efficiency of approximately 98%. While in the presence of catalyst, sodium thiosulfate at 26.72 mmol/L had an inhibition efficiency less than 85.0%. The oxidation reaction order of sulfite in the sodium thiosulfate was determined to be —1.90 and —0.55 in the absence and presence the catalyst, respectively. Apparent activation energy of oxidation inhibition was calculated to be 53.9 kJ/mol. Pilot tests showed that the consumption rate of thiosulfate agreed well with the laboratory-scale experimental results. Key words: dual alkali; sodium sulfite; oxidation inhibition; sodium thiosulfate Introduction Cs(Iv) is the concentration of S, CM is the concentration of catalyst and C02 is oxygen pressure. The parameters such as oxygen concentration and sulfite concentration were confirmed consistently both in homogeneous and hetero geneous system by theoretical and experimental studies. Howe