聚醚改性有机硅表面活性剂的合成与性能.pdfVIP

·10· 何 婷等，聚醚改性有机硅表面活性剂的合成与性能 Vol． 35，No． 4 ，2013 聚醚改性有机硅表面活性剂的合成与性能 何 婷， 季永新 * （南京林业大学化学工程学院，江苏 南京 210037） 摘要：以含氢硅油与端烯丙基聚醚为原料，在氯铂酸的催化作用下，经硅氢加成反应合成了聚醚改性有机硅乳化剂。通过 正交实验测定反应的转化率，探讨了反应时间、反应物比例、催化剂用量以及反应温度对反应的影响，并得出较适宜的反应条 件为：反应时间为7h，n(Si-H)∶n(C=C)=1∶1，催化剂用量为20μg/g，反应温度为130℃ ，在该条件下，含氢硅油中Si-H的转化 率达96%。由此制备的表面活性剂能有效降低表面张力，具有优良的乳化性能。初步讨论了含氢硅油与聚醚反应生成的共聚物 的阴离子化反应，合成了硫酸盐型阴离子表面活性剂，由于结构的差异，产物HLB值有所增加。 关键词：聚醚改性有机硅；硅氢加成；非离子型乳化剂；阴离子型乳化剂 中图分类号：TQ423.92 文献标识码：A 文章编号：1001-0017(2013)04-0010-05 Synthesis and Properties of Polyether Modified Silicone Surfactant HE Ting and JI Yong-xin (Department of Chemical Engineering, Nanjing Forest University, Nanjing 210037, China) Abstract: With using silicone oil containing hydrogen and allyl terminated polyether as raw material and chloroplatinic acid as catalyst, the polyether modified silicone emulsifiers is synthesized through the hydrosilylation reaction. By determining the conversion rate of the reaction with orthogonal experiment, the effects of reaction time, ratio of reactants, amount of catalyst and the reaction temperature on the reaction are discussed. And the appropriate reaction conditions are obtained as follows: the reaction time is 7h, n (Si-H): n (C = C) = 1:1, the amount of catalyst is 20 μg/g, the reaction temperature was 130℃ . Under these conditions, the conversion of Si-H in silicone oil is 96%. The prepared surfactant from this can effectively reduce the surface tension and has excellent emulsification performance. A preliminary discussion of the anion reaction of the copolymer formed by the reaction of the silicone oil and polyether is presented, and