法制备燃料电池催化剂毕业论文.docVIP

液氮冷冻升华还原法制备燃料电池催化剂 理学院应用化学系：付位刚 指导教师：尹鸽平 摘 要：本文对冷冻干燥法制备Pt/C催化剂展开研究。主要从碳载体的不同处理方法和分散剂不同配比对催化剂性能的影响这两个方面进行了探索，并与热干燥法制备的催化剂的性能进行了比较。结果表明，以氧化处理的碳为载体，用300mL超纯水洗涤，冻干法制备的催化剂比热干法制备的催化活性较高；本文还用热干燥法制备了Pt/CNTs催化剂，并与Pt/C催化剂性能进行了比较。结果表明，Pt/CNTs性能好于Pt/C催化剂。 关键词：燃料电池；冷冻干燥；电催化；Pt/C催化剂；Pt/CNTs催化剂 Abstract: The freeze-drying technology and its application in preparing Pt/C catalysts were investigated. The emphases were focused on the influence of the pretreatment of carbon and the amount of dispersant on catalysts. The Pt/C catalysts prepared by freeze-drying and heat-drying were compared. While using carbo