有机质谱-公开课件（讲义）.pptVIP

* * 第二章 有机质谱 Mass Spectroscopy, MS Organic Mass Spectroscopy, OMS 烷烃：CnH2n+1(主)，m/z 29，43, 57, 71, 85, 99, 113, CnH2n, CnH2n-1 环烷烃：41, 55, 56, 69, CnH2n-1，CnH2n 烯 烃：CnH2n-1(主), 如 m/z 41, 55, 69, 83, CnH2n，CnH2n+1 环烯：54， 68，CnH2n-2，CnH2n-3， 醇：CnH2n+1O，31，45，59，CnH2n+1，CnH2n-1 (M-18-28, M-18)，CnH2n-2 醚：CnH2n+1O 的含氧碎片, 31, 45, 59，CnH2n +1 43, 57, 71, 85, 99,113，CnH2n ,CnH2n -1 峰 硫醇:M-33(-HS),M-34(-H2S),33 HS+,34H2S+·，CnH2n+1S 的含硫碎片,47,61,75,89···.CnH2n +1 (43,57,71,85,99,113 ···), CnH2n和CnH2n-1 胺：CnH2n+2N 的含N特征峰,30,44,58,···30+14n. 芳香族：M+·强或中等强度。91强峰，γ-H重排 92峰，52或 66，40或65，39峰或77，78，51