水-环己烷-乙醇体系的液液平衡研究-高校化学工程学报.pdf

20 4 No.4 Vol.20 2006 8 Journal of Chemical Engineering of Chinese Universities Aug. 2006 1003-9015(2006)04-0643-05 -- , , , ( , 215500) GC-14B --298.15K308.15K318.15K 328.15K 1.51% -- -- -- O657 A Liquid-Liquid Equilibrium of the Water-Cyclohexane-Ethanol System JU Hong-fang, XU Hua, SHAO Yan-fang, YING Wen-yi (Department of Chemistry, Changshu Institute of Technology, Changshu 215500, China) Abstract: Under normal pressure, the isothermal LLE data of water-cyclohexane-ethanol (H O-C H -C H OH) 2 6 12 2 5 system at 298.15K, 308.15K, 318.15K and 328.15K were measured, respectively, by using the gas chromatograph method. The inner-scaling method was used to determine the concentration of C6H12 and C H OH in this ternary system. During which, the n-butyl alcohol (n-C H OH) was chosen as the diluent and 2 5 4 9 ethyl acetate (CH COOC H ) was chosen as the inner-scaling substance because of its separability and its fit 3 2 5 retaining time. The retaining time of C H , CH COOC H , C H OH and n-C H OH are 1.771 min, 2.550 min, 6 12 3 2 5 2 5 4 9 3.035 min and 5.499 min, respectively, and the relative correcting factors of C H and C H OH are 0.533 and 6 12 2 5 0.837. The measured LLE data at four given temperatures mentioned above and their corresponding isothermal section diagra