碳钢耐候钢在3种典型大气环境中的腐蚀规律研究.pdf

第36 卷 第1 期 中国腐蚀与防护学报 Vol.36 No. 1 2016 年2 月 Journal of Chinese Society for Corrosion and Protection Feb. 2016 碳钢、耐候钢在3 种典型大气环境中的 腐蚀规律研究 汪 川 曹公旺 潘 辰 王振尧 刘淼然 中国科学院金属研究所 沈阳 110016 摘要：针对热带雨林大气，海洋大气和工业大气3 种环境开展碳钢和耐候钢的大气腐蚀规律研究。结果表明， 碳钢和耐候钢在同一地区的动力学规律和产物以及产物间转化规律基本相似，但在不同地区的腐蚀机理差别 很大，碳钢在海洋大气的腐蚀速率极高，该地区碳钢年腐蚀速率分别是工业大气的8.6 倍，是热带雨林大气的 29.4 倍，导致这种差异的原因在于不同地区大气腐蚀特征因子不同。 中图分类号：TG 172.3 文献标识码：A 文章编号：1005-4537(2016)01-0039-08 Atmospheric Corrosion of Carbon Steel and Weathering Steel in Three Environments WANG Chuan, CAO Gongwang, PAN Chen, WANG Zhenyao, LIU Miaoran Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China Abstract: Atmospheric corrosion of carbon steel Q235 and 45#, and weathering steel Corten A was studied in three typical atmospheres at tropic rainforest-, marine- and industrial-exposure sites re- spectively. Results show that the carbon steels and the weathering steel exhibited more or less the same corrosion kinetics, the formation of rusts and their evolution for exposure in one test site. But they were significant different from those for exposure in other test sites. Finally, the influence fac- tors on corrosion process and the corrosivity of the three atmospheres were also discussed. Key words: carbon steel, weathering steel, atmospheric corrosion, conversion of rust, semipermeable membrane 1 前言 化学过程，并且碳钢和耐候钢在腐蚀动力学、腐蚀机 理、腐蚀产物和影响大气腐蚀机制的因素等方面极 钢是国民领域中最基本的结构材料，从原材料， [1-5] 为相似 。美国ASTM 早在1916 年