含铋光催化材料的研究进展.pdfVIP

化 工 进 展 2014 年第 33 卷第 6 期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·1475 · 进展与述评 含铋光催化材料的研究进展 王伟华，叶红齐，覃涛，刘宣业，黄辉，赵炜康，朱坤杰 （中南大学化学化工学院，湖南长沙 410083 ） 摘要：含铋光催化材料因其能吸收可见光、催化活性高而具有广阔的应用前景。本文主要回顾了含铋光催化材 料近年来的研究概况，详细介绍了铋氧化物、卤氧化铋及钛酸铋、钨酸铋、钒酸铋、钼酸铋、铁酸铋等光催化 剂的结构、制备和光催化性能，重点对光催化性能的改进方法进行了综述，包括制备方法的改良、催化剂的掺 杂改性及复合催化剂的制备等；最后针对进一步提高光催化剂整体性能、实现工业化应用两点，提出了未来可 以利用多元元素掺杂、多元半导体复合进行改性和负载于某些载体制备整体催化剂进行改良的观点。 关键词：铋；光催化剂；改良；掺杂；复合 中图分类号：O 643 文献标志码：A 文章编号：1000 –6613 （2014 ）06 –1475 –11 DOI ：10.3969/j.issn.1000-6613.2014.06.020 Recent progress of bismuth-containing photocatalysts WANG Weihua ，YE Hongqi ，QIN Tao ，LIU Xuanye ，HUANG Hui ，ZHAO Weikang ，ZHU Kunjie （School of Chemistry and Chemical Engineering，Central South University，Changsha 410083，Hunan ，China ） Abstract：Bismuth-containing photocatalysts can be used in many fields because of narrow band gap and ability of adsorbing visible light. In this paper ，the latest research status and progress of bismuth-containing photocatalysts are reviewed. Bismuth oxide ，halide bismuth oxide ，bismuth titanate ，bismuth tungstate ，bismuth vanadate ，bismuth molybdate and bismuth ferrite are introduced and the methods of improving photocatalytic performance are highlighted ，including improvement of synthesis methods ，photocatalysts doping and preparation of photocatalyst composites. Finally ，the research directions of bismuth-containing photocatalysts are presented ，aimed at improving overall performance and realizing industrial application of bismuth-containing photocatalysts ，such as preparing multi-doped photocatalysts ，multiple photocat