氨络合法电化学捕集去除城市污泥中重金属的研究.docVIP

氨络合法电化学捕集去除城市污泥中重金属的研究 萧晨霞 1,胡勤海 1*,田 耘 1,裴毓雯 1,张旭 1(1.浙江大学环境工程系,浙江 杭州 300158) 摘要:采用自行设计的电动污泥处理装置,以杭州七格城市污水厂污泥为试验对象,在 18V 恒定直流电压下运行 120h,研究了四组氨水添加比 分别为 0、0.08、0.10、0.12 (V/V, 氨水/试样污泥)条件下,直接利用阳极电解产酸酸化污泥与氨水络合效应对城市污泥中重金属的捕集去除 效果.试验结果表明,阳极酸化对污泥中重金属有一定的溶出作用,氨水的添加对电动修复过程中污泥 pH 值的降低与电流密度没有影响,但能 够有效提高污泥中重金属的捕集去除效果;当氨水添加比为 0.12 时,污泥中 Zn 和 Cu 的捕集去除效果最佳,分别达 91.62%和 71.49%.而 Pb 的 捕集去除率在氨水添加比为 0.08 时最佳,达 47.85%.氨水的添加对污泥中重金属形态和迁移作用有明显影响,主要表现为稳定形态如残渣态 和有机硫结合态的减少,可迁移形态如可交换态的增加. 关键词:城市污泥;重金属;氨水;电动修复 Study on electrokinetic gathering and removal of heavy metals from sewage sludge with ammonia complexation XIAO Chen-xia1, HU Qin-hai1*, TIAN Yun1, PEI Yu-wen1, ZHANG Xu1 (1.Department of Environmental Engineering, Zhejiang University, Hangzhou, Zhejiang 310058, China) Abstract: New version of renovate equipment has been designed to remove heavy metals from municipal wastewater sludge. Four groups of ammonia have been added and mixed with the experiment samples respectively at ratios of 0、0.08、 0.10、0.12 (V/V, NH3 ·H2O/Sludge sample). They were electrified with 120 hours of constant direct voltage at 18V. The impact of heavy metals removal process from sewage sludge on acidification of sludge generated by anode together with ammonia complexation has been studied. The results indicate that acidification generated by anode has a moderate removal rate on heavy metals. While the impact of adding ammonia has no impact on pH decrease and electric current density in electric repair process; but it can effectively trap heavy metals in the sludge to increase the removal rate. Also it is discovered that different additions of ammonia have different levels of influence on electrokinetic remediation: when ammonia was added at a ratio of 0.12, removal rates of Zn and Cu were 91.62% and 71.49% respectively; while the best remediation of Pb is observed at the ratio of 0.08, and the removal rate can reach to 47.85%. The impact of adding ammonia was that it could change the migration process of heavy met