毕业论文设计《碳酸二乙酯乙基化邻苯二酚合成邻羟基苯乙醚的研究》.docVIP

l 碳酸二乙酯乙基化邻苯二酚合成邻羟基苯乙醚的研究 (江苏省安全科学生产研究院，江苏　南京　210042) 摘要：以碳酸二乙酯为乙基化试剂，与邻苯二酚在气固条件下催化合成邻羟基苯乙醚。考察了以NaY分子筛为载体，K2CO3，Mg(OAc)2这两种不同活性组分催化剂的催化性能，着重探讨固体催化剂的酸碱性对催化性能的影响，研究结果表明，碱性越强，产物邻羟基苯乙醚的产率越高，酸性越强，C-乙基化产物的量越高。 关键词：碳酸二乙酯；邻苯二酚；乙基化；NaY分子筛 [中图分类号] O636.1 [文献标识码] A [文章编号] Study on O-hydroxy by ethylation of diethyl carbonate and catechol Ｈe Tianping, Ma Rongsheng (Jiangsu Academy of Safety Science And Technology,Nanjing, Jiangsu 210042) Abstract: Vapor phase ethylation of catechol with diethyl carbonate (DEC) as an alkylating agent has been carried out. The catalytic activities of NaY loaded with K2C