蚀刻液废水厌氧氨氧化脱氮性能研究.pdf

中国环境科学 2012,32(12) ：2199~2204 China Environmental Science 蚀刻液废水厌氧氨氧化脱氮性能研究 李 祥 1,黄 勇 1*,朱 莉 1,袁 怡 1,2,李大鹏 1,张 丽 1 (1.苏州科技学院环境科学与工程学院,江苏 苏州 215011 ；2. 同济大学环境学院,上海 200092) 摘要：采用上流式生物膜反应器接种厌氧氨氧化污泥,研究了印制电路板行业蚀刻液废水厌氧氨氧化脱氮可行性.结果表明,蚀刻液废水作 为 NH4+-N 源时,其所携带的物质对厌氧氨氧化污泥活性具有毒性作用.当蚀刻液废水稀释到NH4+-N 浓度 150mg/L 进入反应器 14d 后,厌 氧氨氧化氮去除速率从3.2kg/(m3 3 ·d)下降到 1.2kg/(m ·d).但是通过驯化培养可以很好地缓解蚀刻液对厌氧氨氧化污泥的毒性影响.经过 110d + 3 的驯化,蚀刻液废水稀释到 NH4 -N 浓度 300mg/L 进入反应器后并未出现明显的抑制现象.厌氧氨氧化氮去除速率从 1.6kg/(m ·d)上升到 6.0kg/(m3·d).说明通过驯化培养后,厌氧氨氧化工艺能够很好的运用到 PCB 行业高 NH4+-N 废水的处理. 关键词：厌氧氨氧化；蚀刻液；毒性；驯化；氮去除速率 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2012)12-2199-06 Study on nitrogen removal performance of ANAMMOX process of etching wastewater. LI Xiang 1, HUANG Yong1*, 1 1,2 1 1 ZHU Li , YUAN Yi , LI Dang-peng , ZHANG Li (1.School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 2150l1, China ；2.College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China). China Environmental Science, 2012,32(12)：2199~2204 Abstract ：The performance of anaerobic ammonia oxidation (ANAMMOX) for nitrogen removal from etching wastewater was investigated using an up flow biofilm reactor by inoculating with ANAMMOX sludge ．The reactor operation results indicate that etching wastewater was toxic to activity of ANAMMOX sludge as NH4+-N source. Nitrogen 3 3 removal rate of ANAMMOX reactor was reduced from 3.2 kg/(m ·d) to 1.2 kg/(m ·d) in 14 days, when the concentratio