《复合Bi2O3TiO2纳米光催化剂的制备及性能研究.docVIP

摘要 PAGE IV 精品 复合Bi2O3/TiO2纳米光催化剂的制备及性能研究 摘 要 二氧化钛具有稳定性好、光催化效率高和不产生二次污染等特点,有着广阔的应用前景。本文首先论述了二氧化钛的氧化机理、光催化性质、一般制备方法、影响光催化效率的实验条件及改性研究，再以钛酸四丁酯和硝酸铋为原料，采用水热法制备了Bi2O3/TiO2纳米光催化剂，并考察了水解条件和Bi2O3掺杂量等制备条件对光催化剂性能的影响。结果表明，当水和乙醇的比例为4:1时所得样品的光催化活性最好；Bi2O3的掺入拓宽了TiO2对光的吸收范围，提高了TiO2的光催化活性，掺入量（Bi2O3）为0.25%复合光催化剂活性最高；复合光催化剂对多种水溶性染料均具有较好的处理效果。 关键词：水热法，纳米二氧化钛，光催化降解，罗丹明B Compound TiO2/Bi2O3 Nanometer Photocatalyst Preparation And Function Study ABSTRACT Titanium dioxide has a good stability, photocatalytic efficiency and does not produce secondary pollution, etc, which have broad application prospects. The paper first discusses the oxidation mechanism of titanium dioxide photocatalytic properties, the general preparation method, the photocatalytic efficiency of the impact of experimental conditions and modification research. Then tetra butyl titivate and bismuth nitrate as raw materials by hydrothermal Bi2O3/TiO2 prepared nanometer photocatalyst, also visited the hydrolysis conditions and the volume of Bi2O3-doped composite preparation conditions on properties of photo-catalyst. The results show that, when the water and ethanol at a ratio of 4:1 sample from the best photocatalytic activity; Bi2O3 incorporation of TiO2 to broaden the range of light absorption and improve the photocatalytic activity of TiO2, incorporation (Bi2O3) 0.25% for the activity of the highest composite photocatalyst; composite photocatalyst on a variety of water-soluble dyes have better treatment effect. KEY WORDS: hydrothermal method, nanometer TiO2, photocatalytic degradation, Rhodamine B 前言 目 录 TOC \o 1-3 \h \z \u 第1章 绪论 1 1.1 TiO2光催化氧化机理 1 1.2 纳米二氧化钛光催化剂的制备方法 2 1.3 二氧化钛的改性研究 3 1.3.1 贵重金属沉积 3 1.3.2 复合半导体 3 1.4 纳米二氧化钛及复合纳米二氧化钛光催化影响因素 4 1.4.1 催化剂投加量 4 1.4.2 纳米Bi2O3 / TiO2光催化剂对多种水溶性染料的降解试验 4 1.5 二氧化钛的应用及前景展望 5 第2章 水热法制备纳米二氧化钛样品及影响因素 6 2.1主要试剂和仪器 6 2.2样品的制备 6 2.3 水和乙醇的配比对Bi2O3/TiO2复合光催化剂催化效果影响 6 2.4 掺杂量对Bi2O3/TiO2复合光催化剂催化效果影响 7 第3章 二氧化钛对罗丹明B的光催化脱色实验 9 3.1催化剂投加量的