《甘薯淀粉系高吸水树脂的制备及性能研究》【毕业设计论文】.docVIP

PAGE II 甘薯淀粉系高吸水树脂的制备及性能研究 化学工程与工艺专业 [摘 要] 甘薯淀粉系高吸水性树脂具有原料易得、生产成本低、环境兼容性好、使用方便等优点，因而被广泛应用于众多领域。 本论文根据自由基接枝聚合原理，利用淀粉与部分中和的丙烯酸接枝共聚制备高吸水性树脂。通过实验系统地研究了合成高吸水性树脂过程中，淀粉与丙烯酸地配比、丙烯酸地中和度、引发剂地用量、反应时间、反应温度及干燥温度等基本工艺条件对吸水性能的影响，并确定了最佳合成工艺。 通过正交实验得出，当淀粉与丙烯酸的配比为1：4.5，引发剂/原料为0.0075：1，反应时间为2.5h，反应温度为60℃，中和度85%，干燥温度120℃时，可得到吸水率最高的接枝共聚产物，其清水吸水率到540倍。 [关键词] 甘薯淀粉 接枝共聚 高吸水树脂 丙烯酸  Study on Preparation and Performance of Super Absorbent Polymer of Sweet Potato Starch Grafted Acrylic Acid Chemical Engineering and Technology Major Li Shi- jie Abstract: Super Absorbent Polymer of Sweet Potato Starch Grafted Acrylic Acid have manyadvantages such as available raw material,lower production cost, good environment compatibility, convenient usefulness, etc.Thus,they are widely applied in numerous fields. According to the principle of the free radicals graft copolymerization,superabsorbent resins were prepared by graft copolymerizing between starch and partly neutralized acrylic acid.The technical conditions of the synthesizing process were systematically studied by experiments,which included,ratio of starch and acrylic acid,neutralized degree of acrylic acid,dosage of initiator,reacting time and temperature,and drying temperature. The optimum technical conditions were determined. According to the result of orthogonal test,The graft copolymer had the highest water sorption at following conditions:the ratio of starch to acrylic acid was 1:4.5,the ratio of initiator to raw materials was 0.0075:1,reacting time was 3h,temperature was 60℃and neutralization degree of acrylic acid was 85%.The water sorption of the product in water was up to 540 times of itself weight. Key words：Sweet potato Starch；Graft co-polymerization；Super Absorbent Polymer；Acrylic acid； PAGE ii 目 录 TOC \o 1-3 \h \z \u 一 绪 论 1 1.1 高吸水性树脂简介 1 1.1.1 高吸水树脂合成方法 2 1.1.2 国内外高吸水性树脂的研究概况 3 1.1.3 高吸水树脂的性质与应用 5 1.2 淀粉系高吸水性树脂 6 1.2.1 淀粉接枝丙烯腈共聚物 7 1.2.2 淀粉接枝丙烯酸(盐)共聚物 8 1.2.3 淀粉接枝丙烯酰胺共聚物 9 1.3 本文研