凝胶-共还原法制备超细Mo-Cu粉末和其烧结性能.PDF

第 17 卷第 3 期 中国有色金属学报 2007 年 3 月 Vol.17 No.3 The Chinese Journal of Nonferrous Metals Mar. 2007 文章编号：1004-0609(2007)03-0422-06 凝胶-共还原法制备超细 Mo-Cu 粉末及其烧结性能 程继贵，弓艳飞，宋 鹏，李 洁 (合肥工业大学 材料科学与工程学院，合肥 230009) 摘 要：以(NH ) Mo O ·4H O 和 CuO 为前驱体，采用有机物辅助的凝胶工艺制得干凝胶。干凝胶经煅烧、还原 4 6 7 24 2 后，获得 Cu 含量为 20%(质量分数) 的Mo-Cu 复合粉末。该 Mo-Cu 粉末模压成形后，在 H2 中于 1 050~1 150 ℃烧 结，制得 Mo-Cu 复合材料。通过 X 射线衍射， 透射电镜等对干凝胶煅烧后产物及其还原后粉体的相组成、形貌 和粒度等进行了表征；通过扫描电镜观测了不同温度烧结所得 Mo-Cu 复合材料烧结体的显微结构，并对其密度、 电导率和强度等物理力学性能进行了测定。结果表明：通过凝胶-共还原法可以制备分散均匀、平均粒度为 200 nm 的Mo-Cu 超细粉末; 该 Mo-Cu 粉末烧结活性高，其成形压坯在 1 150 ℃下于 H2 气氛中烧结 90 min 后相对密度可 达 99.65%，且烧结体的晶粒细小均匀，具有良好的物理力学性能。 关键词：Mo-Cu 复合粉末；超细颗粒；凝胶-共还原法；烧结行为 中图分类号：TG 146.412 文献标识码：A Characterization and sintering behavior of ultra-fine Mo-Cu powder prepared by gelatinization-coreduction method CHENG Ji-gui, GONG Yan-fei, SONG Peng, LI Jie (School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China) Abstract: Mo-Cu composite powders were prepared by gelatinization-coreduction method, in which gels were obtained from precursors of (NH ) Mo O ·4H O and CuO powders. The gel was then calcined and H -reduced to convert into 4 6 7 24 2 2 Mo-Cu powders. The phase constitute and morphology of the calcined gel, as well as the Mo-Cu composite powders were characterized by X-ray diffractometry and transmission electron microscopy. Mo-Cu powders were die-pressed and sintered in H2 atmosphere in temperature range of