武汉大学电化学课件 陈胜利 Chaper 4 Transient electrode processes.pptVIP

Chapter 4 Transient Electrode Processes What is transient electrode processes As an electrochemical perturbation is imposed on the electrode/solution interface and the electrode reaction proceeds, concentration gradients of reactant and product will develop and extend gradually in the solution side of electrode/electrolyte interface. Before the steady-state is reached, the local concentrations near electrode surface changes dynamically with time, i.e., ?ci/ ?t ? 0 The concentration change depends on the mode of the electrochemical perturbations imposed on the electrode/electrolyte interface.