武汉大学电化学课件 陈胜利 Chaper 5 Electrode process with complex mechanism.pptVIP

Chapter 5 Electrode Processes With Complex Mechanisms In the foregoing sections, we have assumed that the interfacial reactions proceed through a simple one-step charge transfer mechanism Possible processes involved in an electrode reaction The electrode reaction proceed through a multi-step of electron transfer mechanism If we assume that the steps preceding to and following the rds are under equilibrium The electrode reactions with coupled homogeneous chemical reactions Some electrode reactions have mechanisms in which the interfacial electron transfer does not occur directly between the ele