石墨烯改性聚酰亚胺纳米复合材料强化和摩擦学的效果.pdf

Research Article Modified Graphene/Polyimide Nanocomposites: Reinforcing and Tribological Effects Ting Huang,† Yuanshi Xin,† Tongsheng Li,*,† Steven Nutt,‡ Chao Su,† Haiming Chen,† Pei Liu,† and Zuliang Lai† †State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200433, P. R. China ‡Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, California 90089-0241, United States S *Supporting Information ABSTRACT: By taking advantage of design and construction of strong graphene−matrix interfaces, we have prepared modified graphene/polyimide (MG/PI) nanocomposites via a two-stage process consisting of (a) surface modification of graphene and (b) in situ polymerization. The 2 wt % MG/PI nanocomposites exhibited a 20-fold increase in wear resistance and a 12% reduction in friction coefficient, constituting a potential breakthrough for future tribological application. Simultaneously, MG also enhanced thermal stability, electrical conductivity, and mechanical properties, including tensile strength, Young’s modulus, storage modulus, and microhardness. Excellent thermal stability and compatibility of interface, strong covalent adhesion interaction and mechanical interlocking at the interface, as well as homogeneous and oriented dispersion of MG were achieved here, contributing to the enhanced properties observed here. The superior wear resistance is ascribed to (a) tribological effect of MG, including supp