The barrier property of a polymer material is impacted by the environment, such as temperature, relative humidity, etc. and fickian behavior of the material itself. For Fickian materials (or those that obey Fick’s Law), permeation is linear with concentration for all concentration ranges. Non-Fickian behavior means changes in materials due to polymer and permeant interactions (swelling, plasticizing, etc). Displayed graphically, Fickian and Non-Fickian materials would look like this. PE PP PMMA 有机玻璃 PVC 极性分子 应用举例: 袋装美式火腿官司 被包装产品: 美式火腿 为使肉质鲜嫩, 加工时添加水溶液,故产品含水量高. 包装后, 袋中RH =75% 包装袋材料: Nylon/
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