用py-gc-ms 法研究含硼及磷化合物对紫椴木质素热解产物.docVIP

Proceedings of International Symposium on Research Effective Utilization of Bio-based Materials 中国林学会木材科学分会第十次学术研讨会论文集 PAGE 362 PAGE 367 用Py-GC-MS法研究含硼及磷化合物 对紫椴木质素热解产物组成的影响 陈琳1 王清文2 隋淑娟2 佟晓磊2 （1.东北林业大学理学院；2. 东北林业大学生物质材料科学与技术教育部重点实验室，哈尔滨 150040 ） 摘要： 采用裂解-气相色谱-质谱（Py-GC-MS）联机分析技术研究了含硼及磷化合物对紫椴木质素热解产物组成的影响。主要结论是：紫椴木质素热解产物中挥发性有机化合物的比例较大，而经硼酸和有机磷磷酸盐处理过的木质素在裂解过程中，挥发性有机化合物的比例明显减少；含硼化合物可能有促进CO2释放的作用，硼酸有促进异构化、脱氧的作用，而硼酸钠对异构化的作用较小；无机磷酸盐对木质素热解过程中生成醇、醛等小分子化合物有促进作用，磷酸脒基脲（GUP）有机磷酸盐对热解过程中生成芳香族、稠环、杂环化合物有促进作用；FRW阻燃剂中GUP和硼酸对影响木质素的热解过程有协同作用。初步鉴定了紫椴木质素裂解产物中103种化合物的结构。 关键词： Py-GC-MS；紫椴；木质素；热解产物 Study on the Influence of Boron Compounds and Phosphates on the Pyrolysis Products of Tilia amurensis Lignin by Py-GC-MS Method CHEN Lin1, WANG Qing-wen2, SUI Shu-juan2, TONG Xiao-lei2 (1. Science College, Northeast Forestry University, Harbin 150040) (2. MOE Key Laboratory of Bio-based Material Science and Technology, Harbin 150040) Abstract: The pyrolysis products of tilia amurensis lignin treated by boron compounds and/or phosphates were analyzed by pyrolysis gas-chromatography mass-spectroscopy (Py-GC-MS). The Influence of the chemicals on the comparison of pyrolysis products of tilia amurensis lignin was discussed. The pyrolysis of untreated lignin produced more volatile pyrolytic products than that of boric and organic phosphates treated lignin. Boron compounds might promote carbon dioxide releasing. Boric acid could more easily make lignin to form aromatic structure and oxygen- elimination than borates. Inorganic phosphates made lignin to form more aliphatic compounds, while Guanylurea phosphate (GUP) made lignin to form more aromatic compounds. GUP and boric acid in Fire-retardant FRW were synergistic in influencing the pyrolysis process. 103 compounds in the pyrolysis products of tilia amurensis lignin were identified. Keyword: Py-GC-MS, tilia amurensis , lignin, pyrolysis products 1 前言 木质素是木材的主要化学成份之一。它具有芳香族特性的、非结晶的、三维空间结构的高聚物。木质素的基本结构单元有三种：愈疮木基丙烷（G）、紫丁香基丙烷(S)、对羟苯基丙烷(H)，紫椴等阔叶树木质素的结构单