SERS简介心得分享.ppt

a 1ppmCV, b Fe3O4@Ag+1ppm CV c b +10μmol L-1 GSH. 线性范围5×10-8~7×10-7 mol L-1 检出限 4×10-8 mol L-1 线性及检出限 批次重现性 RSD=7.1% 重现性好 可控制备 方法稳定 重现性 * 2.2 发展方向-实际应用 2.2.1 快速检测 痕量分析 2.2.2 免疫识别 2.2.3 理化指标检测 2.2.4 生物成像 临床诊断 2.2.1 快速检测 痕量分析 Adv. Mater. 2013, 25, 3554–3559 ACS Nano, 2009, 3, 2329–2339. 2.2.2 免疫识别 Nano Lett., 2007,7, 2819–2823. 2.2.3 理化指标检测 温度，离子强度，pH等 Nat. Biotechnol., 2008, 26, 83–90. 2.2.4 生物成像 临床诊断 特殊组织，细胞，癌细胞成像 药物释放监测，药理研究 实验结合计算进行理论研究 高效基底制备 联用技术（HPLC-SERS, TLC-SERS） 简便测试方法（便携式拉曼，在线监测) 实际应用（环境污染物，食品添加剂） 生物成像 热点及发展趋势 我们的方向 简单的方法制备高效基底 应用于环境污染物或食品添加剂的检测 揭示其化学本质 反馈 Related work in our lab Dependence of electronic structure of g-C3N4 on the layer number of its nanosheets: A study by Raman spectroscopy coupled with first-principles calculations Novel One-pot Fabrication of Lab-on-a-Bubble@Ag Substrate without Coupling-agent for Surface Enhanced Raman Scattering Micro/nano-structured graphitic carbon nitride-Ag nanoparticle hybrids as new SERS substrates Three-Dimensional Plasmonic Hydrogel Architecture: Facile Synthesis and Its Macro Scale Effective Space A surface-enhanced Raman scattering method for detection of trace glutathione on the basis of immobilized silver nanoparticles and crystal violet probe Dependence of electronic structure of g-C3N4 on the layer number of its nanosheets: A study by Raman spectroscopy coupled with first-principles calculations Jizhou Jiang, Lei Ou-yang, Lihua Zhu, Anmin Zheng, Jing Zou, Xianfeng Yi， Heqing Tang, Carbon, 2014,80, 213–221. Figure S3 Schematic illustration of concentrated-H2SO4 intercalation-exfoliation process from coplanar bulk g-h-heptazine-C3N4 to ultrathin layers. 制备不同层数的氮化碳 * 520 oC, 4 h, air + 三聚氰胺 多层氮化碳 (g-C3N4) 剥离 1、2、4层氮化碳 * 单层和多层的Raman图谱区别 两组峰的比值随层数的变化规律 峰位移与层数的变化规律 Novel One-pot Fabrication of Lab-on-a-Bubble@Ag Substrate without Coupling-agent for Surface Enhanced Raman Scattering Jizhou Jiang, Lei Ou-Yang, Lihua Zhu, Jing Zou, Heqing Tang. Scientific reports,