金属有机骨架材料在CO_2_CH_4吸附分离中的研究进展_张所瀛.pdfVIP

65 5 Vol.65 No.5 May 2014 2014 5 CIESC Journal 1 CO /CH 2 4 1 1 1 1 1 2 1 1 210009 2 100029 CO2/CH4 metal organic frameworksMOFs CO CO 2 2 MOFs MOFs CO /CH 2 4 CO CH 2 4 DOI 10.3969/j.issn.0438-1157.2014.05.002 O 6-1 A 04381157201405156308 Progress of adsorption-based CO /CH separation by metal organic frameworks 2 4 1 1 1 1 1 2 1 ZHANG Suoying , LIU Hong , LIU Pengfei , WU Peipei , YANG Zhuhong , YANG Qingyuan , LU Xiaohua 1 ( State Key Laboratory of Materials-Oriented Chemical Engineering, School of Chemical Engineering, Nanjing Tech University , Nanjing 210009, Jiangsu, China; 2State Key Laboratory of Organic-Inorganic Composites, School of Chemistry and Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China) Abstract: The high energy penalty of CO2 separation from biogas is a core problem in the biomethane process. Metal organic frameworks (MOFs) have recently attracted intense research interest because of their ultra-high CO2 adsorption capacity and potential applications as novel adsorbents to reduce energy cost. The recent