09极限性能_新课件.pptVIP

9.5.1 Griffith理论 9.6 增强与增韧 结晶聚合物冷拉模型II 拉伸PE纤维的TEM (a)0% (b)400% (c)600% 9.4 银纹 Craze: narrow zones of highly deformed and vioded polymer Optimists concentrate on plastic deformation in crazes as a source of toughness or stress relief in polymers, while pessimists focus on crazing as the beginning of brittle fracture 银纹的结构 Craze thickness, ?m Distance from center of craze, ?m Force Force –100 -50 0 50 100 0.50 0.25 0 ~200? ~80 ? 银纹不空，其中为被拉伸的链 银纹中的链有50~60%的伸长率 银纹中链的体积分数为40~60% 银纹仍有模量，约为本体的3~25% 银纹是可逆的，能通过退火消除 银纹的本质：张力作用下链段