微乳液法用于纳米金属氧化物催化剂制备.ppt

微乳液法制备纳米二氧化钛及其光催化活性,牛新书,功能材料,34(2003)548 所得产物为纳米微粒且颗粒分布均匀\细小, 平均粒径为10nm 左右,催化性能好 六铝酸钡( BHA )是一种较有应用前景的高温燃烧催化材料。2000 年在《 Nature》 上报道采用微乳法成功地合成了目前世界上最大比表面、 最高甲烷催化燃烧活性的六铝酸钡。其中微乳法制备的BHA 催化剂的甲烷催化燃烧活性远远高于溶胶-凝胶法制备的BHA 催化剂。用微乳法合成的六铝酸钡-CeO2, 催化活性进一步增强, 甲烷燃烧的起燃温度在400℃左右, 600℃时甲烷转化率己达到100%的转化率。 制备复合氧化物纳米催化剂 核壳结构纳米材料制备 The synthesis of silica and silica-ceria, core-shell nanoparticles in a water-in-oil (W/O) microemulsion composed of heptane and water with the binary surfactants AOT and NP-5 Sang-Ho Chung , Dae-Won Lee , Min-Sung Kim , Kwan-Young Lee Journal of Colloid and Interface Science 355 (2011) 70–75 The synthesis of silica and silica–ceria, core–shell nanoparticles in a water-in-oil(W/O) microemulsion composed of heptane and water with the binary surfactants AOT and NP-5 Sample preparation Fig. 1. The two steps for the growth of silica in a water/oil microemulsion: (a) the diffusion of the TEOS through the interface of the micelle droplet and (b) the intermicellar exchange of the partially hydrolyzed TEOS (silanol intermediates). The symbol ‘‘S’’ means a silanol intermediate (Si(OR)3x(OH)x). Oil Surfactant TEOS Diffusion s s s Interaction polycondensation Schematic diagram of the preparation of the silica–ceria, core–shellnanoparticles. TEOS in(AOT+NP-5)/heptane/water microemulsion SiO2 Add APTES Reacted for 24 h SiO2 NH2 NH2 NH2 NH2 NH2 NH2 CeO2 Add Ce(NO3)3 W/O microemulsion Reacted for 24 h The effect of the surfactant molar ratio between AOT and NP-5 on the size of the microemulsion droplets and resulting silica nanoparticles with a 100-mL total reaction volume, 0.1 M total concentration of surfactant, 0.0235 M TEOS and 0.432 M aqueous ammonia. The average droplet size was measured by DLS analysis,and the size of the silica particle was determined from the TEM images. 微乳液法制备负载型纳米催化剂 制备纳米催化剂过程中将载体加入到微乳液中，使生成的纳米粒子附着在载体上，便制得了负载型催化剂。由于载体对纳米粒子的吸附作用，会减少颗粒之间的聚集，因此载体的加入方式对纳米催化剂颗粒的分散度将产生影响。 分离是微乳液法制备负载型催化剂的关键点 催化剂颗粒必须与载体有足够强的粘合力 添加溶剂 新方法 Spraying the micro