芭蕉芋渣对亚甲基蓝的动态吸附研究.docVIP

第 27卷　第 1期 2011年 1月 福建师范大学学报 (自然科学版 Jo ur nal of F ujian N or mal U niver sity (Nat ur al Science Edition V ol. 27　 N o. 1Jan. 2011文章编号 :1000-5277(2011 01-0067-05 芭蕉芋渣对亚甲基蓝的动态吸附研究 卢玉栋 , 叶　琳 , 吴宗华 , 林筱璇 (福建师范大学化学与材料学院 , 福建 福州　 350108 　　摘要 :利用芭蕉芋渣填料柱对水 中亚甲基蓝 (M B 进行动态吸 附 . 探讨了初始质量浓度、 床层高度、 pH 值等因素对穿透曲线的影响 , 运用数学模型对在不同层高和质量浓度下的吸附数据进行拟合 . 结果表明 , 芭 蕉芋渣能有效去除水中的亚甲基蓝 , 随着床层高度的 增高、 pH 的增大和初始质量浓度的减小 , 芭蕉芋渣 填 料柱对水中亚甲基蓝的吸附穿透曲线位点向 右移 . 通过数学模型得到的速率常数、相关系数、 平衡吸附量和 动力学参数 , 能较好地描述芭蕉芋渣填料柱吸附亚甲 基蓝的吸附动力学 . 关键词 :芭蕉芋渣 ; 亚甲基蓝 ; 动态吸附 ; 穿透曲线 ; 数学模型 中图分类号 :T Q 424　　　文献标识码 :A 　收稿日期 :2010-09-07　基金项目 :福建师范大学横向项目 (DH-585 ; 福建师范大学本科生课外科技计划项目 (BKL2010-033 :(:Methylene Blue Removal from Aqueous Solution by Canna Edulis Kerl Residual in Fixed -bed Column LU Yu -dong , YE Lin , WU Zong -hua , LIN Xiao -xuan (Colleg e of Chemistry and M ater ials S cience , Fuj ian N ormal Univ er sity , Fuz hou 350108, China Abstract :T he capability o f canna edulis kerl residual to adsorb methy lene blue (M B fr om aqueous so lution w as investigated in a fix ed -bed column . T he effects of important param eters on breakthro ug h curv e, such as the filler height, pH and concentr ations of M B w er e studied. Mathem atical dynamic m odel respectiv ely at differ ent filler height, different pH and different concentrations of hig h-lay er adsorption data were applied to simulate column adsorption data and to o btain r elevant parameters . T he results show ed that canna edulis kerl residual as an adso rbent to remo ve the MB w as efficient . As the filler heig ht , the pH increasing and density increasing , the breakthro ug h point in the breakthrough curv es mo ved to right. The rate constants, correlatio n coefficients, equilibr ium adsorption capacity and kinetic par am eters, which w ere calculated through mathem atical m odels, can be used to describe the adsorption kinetics of M B by canna edulis kerl residual well. Key words :canna edulis ker l residual; m ethylene blue; dynamic adso rption; br eakthr oug h