北京大学电分析电化学反应动力学elect3a.pptxVIP

Double layers are characteristic of all phase boundaries1V, 1nm, the field strength (gradient of potential) is enormous - it is ofthe order 107 V/cm. The effect of this enormous field at the electrode-electrolyte interface is, in a sense, the essence of electrochemistry!Helmholtz 内层(IHP, inner Helmholtz plane)和 Helmholtz外层(OHP， outer Helmholtz plane)从此图可得到一个具体的双电层大小的概念：双电层中的紧密层厚度大约是3A，分散层约8A，整个双电层约11A或稍大于11A。这虽是汞/溶液界面情况其它电极的双电层尺寸也大致如此。 Chapter Four Fundamentals of Kinetics and Mechanism of Electrode Reactions1. Introduction2. The mechanism of electron transfer at an electrode3. The theory of e