催化化学英文版.pptxVIP

多相催化研究方法 ;催化反应动力学;Monitoring of Reactions ;Near Infrared Spectroscopy ;UV/vis spectroscopy;Raman spectroscopy ;Summary of main data analysis techniques;It is of interest to consider the ways in which the presence of zirconia either as a support or an additive enhances the rate of methanol synthesis. zirconia promotes the rate of methanol formation occurring on the surface of Cu, or alternatively Cu promotes the synthesis of methanol over zirconia. Which of these two options offers the most plausible explanation.;Infrared spectra taken during exposure of Cu/SiO2 to 0.16 MPa CO2 and 0.49 MPa H2.;Infrared spectra taken for Cu/SiO2 at 523 K after switching the feed from 0.65MPa H2 to 0.16 MPa CO2 and 0.49 MPa H2 at 523 K.;Temporal Resolution of Surface Species Transient spectra were obtained after switching the feed fromH2 to 3/1H2/CO2 at a total pressure of 0.65MPa while maintaining the temperature of the Cu/SiO2 catalyst at 523 K. The results are shown in Fig. 3. b-HCOO–Cu (2927,2849, 1540, 1350 cm°1), and weak features for adsorbedCO onCu(2128, 2094, 2077cm°1, not shown) form immediately upon switching and the intensities of the bands for these species remain relatively constant during the 22.6 h transient. At 2.7 min into the transient, a peak at 2959 cm°1 begins to grow in and increases in intensity during the remainder of the transient. This feature is ascribable to CH3O–Si and the companion peak at 2856 cm°1 is evidenced by the asymmetry of the peak at 2849 cm°1 (shoulder on the left). CH3O–Si is also evidenced by the shoulder at 2994 cm °1and the bending mode observable at 1464 cm°1 at longer times. These features forCH3O–Si have been observed during methanol adsorption on Cu/SiO2.;Infrared spectra taken during exposure of ZrO2/SiO2 to 0.16 MPa CO2 and 0.49 MPa H2;The principal features at 323 K are those for b-HCO3–Zr (1619 cm°1) and i-CO3–Zr (1442cm°1).Asmall amount of m-CO3–Zr (1382cm°1) and b-CO3–Zr (1351 cm°1(sh)) are also present. As the temperature is inc