ghs《全球化学品统一分类和标签制度》英文版附件4：编制安全数据单指导.docVIP

Copyright@United Nations, 2009. All rights reserved. ANNEX 4 GUIDANCE ON THE PREPARATION OF SAFETY DATA SHEETS (SDS) - 403 - Copyright@United Nations, 2009. All rights reserved. Copyright@United Nations, 2009. All rights reserved. Annex 4 GUIDANCE ON THE PREPARATION OF SAFETY DATA SHEETS (SDS) A4.1 Introduction A4.1.1 This annex provides guidance on the preparation of an SDS under the requirements of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). SDS’s are an important element of hazard communication in the GHS, as explained in Chapter 1.5. Use of this guidance document should support compliance with competent authority (CA) requirements and should allow the SDS to be prepared in accordance with the GHS. A4.1.2 The use of this guidance document is dependent on importing countries requirements for SDS. It is hoped that the application of the GHS worldwide will eventually lead to a fully harmonized situation. A4.1.3 Unless otherwise stated, all chapters, sections and tables referred to in this annex can be found in the main text of the GHS. A4.2 General guidance for compiling an SDS A4.2.1 Scope and application Safety Data Sheets (SDS) should be produced for all substances and mixtures which meet the harmonized criteria for physical, health or environmental hazards under the GHS and for all mixtures which contain ingredients that meet the criteria for carcinogenic, toxic to reproduction or target organ toxicity in concentrations exceeding the cut-off limits for SDS specified by the criteria for mixtures (see Table 1.5.1 in Chapter 1.5). The competent authority (CA) may also require SDS for mixtures not meeting the criteria for classification as hazardous but which contain hazardous ingredients in certain concentrations (see Chapter 3.2). The CA may also require SDS for substances or mixtures that meet the criteria for classification as hazardous for non-GHS classes/end-points. An SDS is a well-accepted and effective method