担载型催化剂制备中液固.pptVIP

The role of the liquid-solid interface in the preparation of supported catalysts Outline Introduction Preparation of supported catalysts The liquid-solid interface chemistry The contribution of interface science to catalysis Closing remarks Perspective Catalyst Interface Science Preparation of Supported Catalysts via interfacial deposition non-porous support porous support the size of the supported particles the intensity of the supported particles/support interactions Impregnation (1) Filtration (2) Drying (3) Air-calcination (4) Sulphided catalyst Oxidic catalyst activation (5) Metallic catalyst + precipitating agent General preparation scheme of supported catalysts grain interface deposition bulk deposition porous interface deposition bulk deposition non-porous Modes of interfacial deposition Electrostatic adsorption Formation of inner sphere surface complexes electrostatic adsorption through ion pair formation in the outer plane of the compact region of the interface electrostatic adsorption through ion pair formation in the inter plane (or in the inner layers) of the compact region of the Interface (very low probability) Retention the compact region of the interface exclussively through hydrogen bond formation Surface dissolution of the support and formation of mixed Solid phases Surface or interface oligomerization, polymerization and precipitation M1 M4 M5 M7 M6 M2 M3 Increasing specificity pH Concentration of the TMIS Ionic strength Impregnation temperature Impregnation time The liquid-solid interface chemistry Surface ionization models One site / two pK model chanrge of surface oxygen: -1,0,1 One site / one pK model chanrge of surface oxygen: -1/2,1/2 MUSIC model (Multi Site surface Complexation model) chanrge of surface oxygen: -1/3,1...... Determination of the extent of adsorption at various pH values and constant initial concentration and ionic strength Performance of adsorption edges at vario