无机化学课件08 group VA.pptxVIP

Group V A or 15nitrogen, phosphorus, arsenic, antimony and bismuthHydride: AmmoniaOxides月月胂弟 必stability high lowbasicity high lowmp. bp. low highCompounds of As, Sb and BiHydrides: AsH3 SbH3 BiH3spontaneous ignition：pyrolysis：Identification of As：Marsh test ： Mix sample, Zn and dilute HCl or H2SO4，produced gas passes through hot glass tube。Arsenic MirrorGutzeits test ：microscaleOxides and Their HydratesOxides and Hydroxides of M(III)Amphotericity：hydratesunstableOxides and Hydroxides of M(V)medium weakRedox PropertiesM(III) as Reductants (Decrease from As to Bi)Cl2 can be substituted by