SANS谱仪及原理-刘栋.pptVIP

SANS-Sunani谱仪介绍文章 SANS-Sunani谱仪最新参数指标 Since 2017 Neutron flux at the sample position as a function of wavelength L. Chen et al., 2018_JINST_13_P08025 SANS-Sunani谱仪最新参数指标 accessible q-range L. Chen et al., 2018_JINST_13_P08025 各类原位环境装置 Flow-induced crystallization with X-ray scattering SAXS SANS Chain Conformation? Precursor? Liangbin Li*, Chemical Reviews. 2018,?118?(4), 1840–1886 Dong Liu*, Polymer Crystallization. 2018; doi.org/10.1002/pcr2. 10043 (Users from University of Science and Technology of China ) The extensional rheo-SANS measurement of dPE/hPE blend provide the unambiguous orientation of chain segment, direct evidence for the assumption of flow induced nucleation Flow-induced crystallization with X-ray and neutron scattering 几种典型应用- Nucleation of Polymers Liangbin Li*, Macromolecules, 2016, 49 (23), 9080 Dong Liu et al, Macromolecules. 2013,46,3435 By 刘栋 几种典型应用- nanocomposites 最优填料区间：40-50 phr之间 模量平台；断裂应变最大 双应变硬化 技术手段：中子散射 散射数据规律定量解析 实空间电镜观测验证 D Liu et al. Comp. Sci. and Tech. 2018 165 373–379 垫层关键参数获取研究（最优填料比，宏观性能-微结构关联） By 刘栋 SANS 几种典型应用-photoelectric material Y Zheng, L Zou, J Pei, et al. Adv. Mater. 2017. 10.1002/adma.201701072 (Domestic research) Good solvent: One-dimensional worm-like chain Poor solvent: Two-dimensional lamellar structure SANS data SANS data Fitting paremeters Model BDPPV BDOPV has the higher efficiency (carrier migration rate increases 104) than the original material. SANS find that the two type polymer structure lead to a huge difference in performance ? By 邹林 研究意义：纳米粒子和高分子之间的相互作用是影响胶体粒子-聚合物复合材料性能的重要影响因素。研究剪切场下的胶体-高分子之间的竞争吸附行为对于多组分体系的胶体-聚合物材料的性能研究可以提供关键性的指导数据。 SANS 几种典型应用-剪切场下高分子竞争吸附行为 剪切场下同一高分子对不同纳米粒子的竞争吸附行为 剪切场下不同高分子对同一纳米粒子的竞争吸附行为 长时间剪切后达到平衡 外加剪切并引入新粒子 外加剪切并引入另一高分子 长时间剪切后达到平衡 By 朱智超 信息获取联系我们 npl@caep.cn Key Laboratory of neutron physics website CMRR has been recorded in Neutronsources.org 中子小角散射适用范围广，用处大，优势多； 实验相对容易，分析相对困难（模型众多）； 从文献调研样本中看，Matching所占比例相对大； 中子小角散射是强有力的研究手段，但其结果需要其他手段的配合。如：USANS，SESANS，SAXS，WAXD，