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Copyright@United Nations, 2009. All rights reserved.
ANNEX 4
GUIDANCE ON THE PREPARATION OF
SAFETY DATA SHEETS (SDS)
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Copyright@United Nations, 2009. All rights reserved.
Copyright@United Nations, 2009. All rights reserved.
Annex 4
GUIDANCE ON THE PREPARATION OF
SAFETY DATA SHEETS (SDS)
A4.1 Introduction
A4.1.1 This annex provides guidance on the preparation of an SDS under the requirements of the
Globally Harmonized System of Classification and Labelling of Chemicals (GHS). SDS’s are an important
element of hazard communication in the GHS, as explained in Chapter 1.5. Use of this guidance document
should support compliance with competent authority (CA) requirements and should allow the SDS to be
prepared in accordance with the GHS.
A4.1.2 The use of this guidance document is dependent on importing countries requirements for
SDS. It is hoped that the application of the GHS worldwide will eventually lead to a fully harmonized
situation.
A4.1.3 Unless otherwise stated, all chapters, sections and tables referred to in this annex can be
found in the main text of the GHS.
A4.2 General guidance for compiling an SDS
A4.2.1 Scope and application
Safety Data Sheets (SDS) should be produced for all substances and mixtures which meet
the harmonized criteria for physical, health or environmental hazards under the GHS and for all mixtures
which contain ingredients that meet the criteria for carcinogenic, toxic to reproduction or target organ
toxicity in concentrat
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