碳氮薄膜光学带隙和光学性质.ppt

Optical gap and optical behavior in carbon nitride films 与E振动模相应的第一个峰(位于约1580cm-处)常称为G 峰,而与无序碳结构相应的第二个峰(位于1360cm↓处)常称为 D峰。在无定形碳情况下,“G并不意味着石墨。G模式是来自任 偭一对的sp2晶格格位的伸缩振动,芳香环或链;D模式仅是sp2在 环晶格格位的呼吸模。无序引起的D峰和E2振动模引起的G峰的 强度比R=I(D)(G是对样品无序很敏感的表征,得出面内晶粒 大小L。与I(D)/(G成反比关系,即可以用R来描述薄膜中无序sp 团簇的数量和大小。G峰可以用Bret- Wigner-Fano(BWF线性拟 合,D峰可以用 Lorentzian线性拟合,峰强比值I(D)/I(G就可以得 到。I(D)(G)对于aC薄膜的光学带隙是一个重要的参数 I(D)/I(G) (8ap) 另外R与电阻抗,热传导(7)和磁阻抗(8)也有紧密关系。 (7)Heremans ]. Electrical conductivity of vapor-grown carbon fibers Carbon,1985,23:431 (8)Rahim I Sugihara K, Dresselhaus M SHeremans ]. Magnetoresistance of graphite fibers. Carbon 1986, 24: 663 The number of frequencies expected: in the Raman spectrum of single crystals of graphite can easily be enumerated. There are four atoms in the unit cell so the phonon dispersion relation will reveal nine optical branches. Raman (or infrared) activity for a crystal can only be observed in the limit where the wave vector k=0. The unit cell has a symmetry consistent with the space group Da. The point group homorphic with this space group is Dh. From the properties of this point group and the requirement that all unit cells must vibrate with the same phase(k=O or corresponding to the totally symmetric mode of the translation lattice the symmetry properties of the normal modes can be calculated. The results are 2B20+2E2+Au+E1 Only the 2E2g modes are expected to be raman active D峰和G峰相应的晶格振动模式 D峰 G峰 文献 Availableonlineatwww.sciencedirectcom scieNCE。REcT ELSEVIER Thin Solid Films 433(2003)119-125 Optical gap in carbon nitride films S.E. Rodilas. S. Mulla. S. Maca.A C. ferrari anstinwio de investigaciones en Materiales, Univers idad Nacional itiunwwnl de mexico, Cinwito exterior s/n, CU Co ENgineering Depurtment, University of Cambridge, Trumpington Street, CB2 /PZ Cambridge, UK 样品的制备: N掺杂的ta-C样品利用双激光束制备: 碳源为单一弯曲滤阴极弧光FCVA,能够制得含 85%的sp3键的taC;氮源为能够产生高密度等离子体 的电子回旋波共振源ECWR ■a-CN样品利用直流磁控溅射制备 总压强为8帕,氮气分压为0,25,50,75,100% 薄膜性质表征 The N-c composition ratio and the