噻唑盐催化的sila-stetter反应.pdfVIP

The Thiazolium-Catalyzed Sila-Stetter Reaction B4 Umpolung Reactivity OM O O R2 O R1 + R2 R3 R1 R3 O R1 H ? O O O ? R3 + R2 R3 R1 R1 R2 O Benzoin Condensation O O O H H Cat. CN + OH O O CN -CN H + CN O CN O CN H OH O Proton Transfer Proton Transfer H HO CN HO CN O Thiazolium-Catalyzed Benzoin R O R S H Ph N O R O H