废旧丁腈胶粉应力诱导脱硫反应的影响因素研究——螺杆转速的影响毕业论文.pdfVIP

南京工业大学本科生毕业设计（论文） 废旧丁腈胶粉应力诱导脱硫反应的影响因素研究—螺杆转速的 影响 摘 要 本文研究了废旧丁腈胶粉应力诱导脱硫反应的影响因素——螺杆转速的影 响。论文中采用废旧丁腈胶粉挤出过程中加入线性高分子（如 EVA）作为溶胀 剂和承载流体，并改变双螺杆挤出机螺杆转速和反应温度的方法研究了过氧化 物、多硫化物及其复合促进剂对废旧丁腈胶粉脱硫反应的影响。考察了脱硫促 进剂品种、反应温度和双螺杆挤出机螺杆转速对废旧丁腈胶粉脱硫产物凝胶含 量的影响。结果表明：螺杆转速在 200rpm到 1000rpm时，随螺杆转速的提高， 凝胶含量呈现先下降后上升的趋势。在复合促进剂 DBPH/420/水，挤出温度为 180℃，螺杆转速为 400rpm 时，废旧丁腈胶粉脱硫产物的凝胶含量为 45.43%， 脱硫效果较好。 关键字 ：废旧丁腈橡胶 高剪切应力 螺杆转速 脱硫 I Abstract Effects of Shear Stress Coming from the Screw Speed of Twin Screw Extruder on Devulcanization of Waste Nitrile Rubber Abstract This paper studies the waste nitrile rubber powder desulfurization reaction of stress-induced factors - the impact of screw speed .This experiment used nitrile rubber powder is used in the extrusion process to linear polymer ( such as EVA) as the swelling agent and carrier fluid and changing the twin-screw extruder screw speed and the reaction temperature were studiedperoxides polysulfides and composite enhancers on waste nitrile rubber powder desulfurization reaction.The effects of different species desulfurization accelerators , twin-screw extruder screw speed and the reaction temperature ondesulfurization products nitrile rubber powder content of the gel . The experimental results show that: in the 200rpm to 1000rpm, with the increase in screw speed,gel content values first decreased and then increased, when 400rpm better desulfurization effect. Key Words: WNBR high shear stress screw speed Desulfurization 摘 要 I Abstract II 第一章 前言 1 1.1 引言 1