Energy Fuels （高分辨率连续光源火焰原子吸收光谱-波长色散x射线荧光光谱测定石油中的硅）.pdf

Article Cite This: Energy Fuels 2019, 33, 215−227 /EF Acquiring Information on the Total Content and Speciation of Silicon in Petroleum Products/Fuels Using High-Resolution Continuum Source Flame Atomic Absorption Spectrometry and Wavelength-Dispersive X‑ray Fluorescence Zofia Kowalewska,*,† Karolina Brzezinska,́ † Katarzyna Cikorska,† Janusz Pilarczyk, ‡ and Łukasz Gosciniaḱ † †Faculty of Civil Engineering, Mechanics and Petrochemistry, Warsaw University of Technology, Łukasiewicza 17, 09-400 Płock, s. Poland e l ‡ c i t WARTER Fuels JSC, Chemikow 5, 09-411 Płock, Poland́ r a ). d e S C h *Supporting Information T s i U l ( b u 5 p 5 : e ABSTRACT: Various chemical forms of silicon (Si) possibly present in petroleum products/fuels were investigated in this 6 r 5 a : h work: low-molecular-mass species with different compositions, structures, and volatilities, as well as a Conostan oil standard, 2 s 0 y t l polysiloxanes, and silicon dioxide. Analysis in xylene solutions was accomplished using wavelength-dispersive X-ray fluorescence a e t 9 a (WD XRF) or high-resolution continuum source flame atomic absorption spectrometry (HR-CS FAAS). Samples were also 1 m 0 i 2 t analyzed using HR-CS FAAS in aqueous solutions after mineralization in a closed microwave-heated system, mineralization in i , g 2 e 2 l an open s