Energy Fuels （火焰原子吸收光谱法-测定生物柴油铁铜锌铝铬）.pdf

Article /EF Determination of Iron, Copper, Zinc, Aluminum, and Chromium in Biodiesel by Flame Atomic Absorption Spectrometry Using a Microemulsion Preparation Method Greici A. Antunes,† Heldiane S. dos Santos,† Yara P. da Silva,† Marcia M. Silva,*́ ,†,‡ Clarisse M. S. Piatnicki,† and Dimitrios Samios† †Instituto de Química, Centro de Combustíveis, Biocombustíveis, Lubrificantes e Oleos, Universidade Federal do Rio Grande do Suĺ (UFRGS), Av. Bento Gonç alves 9500, CP 15003, CEP 91501-970, Porto Alegre, RS, Brazil ‡Instituto Nacional de Ciencia e Tecnologia do CNPq, INCT de Energia e Ambiente Universidade Federal da Bahia, 40170-115̂ . s e Salvador, BA, Brazil l c i t r a ). d C e h ABSTRACT: This work proposes a flame atomic absorption spectrometry (FAAS) method for Fe, Cu, Zn, Al, and Cr T s i U l ( b determination in biodiesel using water in oil (w/o) microemulsion (ME) as a sample preparation method. A less toxic solvent (n- u 9 p 1 : e propanol), instead of those used in the standard method (ABNT NBR 15556), the absence of surfactant, and calibration using 7 r 5 a : h inorganic reference standards were investigated. A ternary phase diagram of biodiesel as oil, water, nitric acid, and n-propanol 2 s 0 y