光学分析法联用实例.pdf

Article pubs.acs.org/ac Simultaneous UV−Visible Absorption and Raman Spectroelectrochemistry David Ibanez,̃ ‡ Jesus Garoz-Ruiz, ‡ Aranzazu Heras, * and Alvaro Colina* Department of Chemistry, Universidad de Burgos, Pza. Misael Banuelos s/n, E-09001 Burgos, Spaiñ S *Supporting Information ABSTRACT: The development of a new device based on the use of UV−vis . bare optical fibers in a long optical path length configuration and the s e measurement of the Raman response in normal arrangement allows us to l c i t perform UV−vis and Raman spectroelectrochemistry simultaneously in a single r a ). d experiment. To the best of our knowledge, this is the first time that a C e h T s spectroelectrochemistry device is able to record both spectroscopic responses at i U l ( b 9 u the same time, which further expands the versatility of spectroelectrochemistry p 4 : e techniques and enables us to obtain much more high-quality information in a 9 r 5 a : h single experiment. Three different electrochemical systems, such as 8 s 0 y t l ferrocyanide, dopamine, and 3,4-ethylenedioxythiophene, have been studied a e t 9 a to validate the cell and to demonstrate the performance of the device. Processes 1 m 0 i 2 t , i that take place in solution can be prop