物理化学 (10)大学物理.pdf

: ss ddGG ddAA AAdd TpTp,, ss ss  Gibbs   1. T : c   c   (8C) c    2. Gibbs 1877 c d RT dc Gibbs ( ) (molm-2) nn nn 0,10,1 0,20,2 sssshh ss  == nn cchh AA =0=0 11 0,10,1 11 ss ss  == nn cchh AA 22 0,20,2 22 ss ss A dG dA dn dn (1) s 1 1 2 2 Tp G A n n (2) s 1 1 2 2 s G ddGG ddAA AAdd ddnn nn dd ss ss 11 11 11 11 ddnn nn dd 22 22 22 22 (1)- Adn d n d 0 s 1 1 2 2