经典工业生产2.ppt

工业生产 PPTA的聚合方法 PPTA的合成有如下几种方法：低温溶液聚合法、界面缩聚法、固相聚合法、气相聚合法、微波辐射聚合法和络合聚合体系。 .精品课件. * 历史 1965年美国杜邦公司的S. L. Kwolek博士开发出间位芳纶“HF-1”， 1966年杜邦公司开发出对位聚芳酰胺纤维，即以后众所周知的Kevlar纤维， 1967年杜邦的间位芳纶开始以商品名“Nomex”出售， 1972年日本帝人公司生产出了间位芳纶，商品名为“Conex”， 1975年荷兰阿克苏公司生产出对位芳纶，商品名“ Arenka”， 1986年阿克苏公司将“ Arenka”更名为“Twaron” ， 1987年日本帝人公司的对位芳纶“Technora”实现产业化， 1991年德国Hochest公司建立了芳香族聚酰胺纤维小试厂。 .精品课件. * 国外现状 美国杜邦（Du Pont） ——Kevlar 荷兰阿克苏诺贝尔公司（Akzo-Nobel，已与日本帝人公司合并）——Twaron 日本帝人公司——Technora 此外，俄罗斯、德国、韩国 帝人(45%) 杜邦(55%) 其他 5％ 对苯二甲酰氯和对苯二胺在NMP中低温溶液缩聚法制备树脂，树脂再溶于浓硫酸中进行液晶纺丝 .精品课件. * 不同厂家生产芳纶结构 .精品课件. * .精品课件. * Teijin Aramid is the leader in the world of aramids. With four different aramids in a variety of formats, we can offer our customers not only the greatest range of product properties, but also an unrivalled level of knowledge and experience when it comes to innovative product development. / Teijin Aramid（帝人） Twaron Sulfron Teijinconex Technora .精品课件. * Twaron（PPTA） Twaron? is a very strong, light para-aramid fiber (poly-paraphenylene terephthalamide) developed and produced exclusively by Teijin Aramid It has a high modulus, and is thermally stable, and highly impact and chemical resistant. .精品课件. * Twaron（PPTA） Main characteristics 1、High tensile strength Strong and light: weight for weight, Twaron is 5 times stronger than steel. 2、Fatigue resistance Little loss of strength during repeated abrasion, flexing and stretching. 3、Dimensional stability Stiff and highly oriented molecular structure leads to a high modulus of elasticity, low creep and low stress relaxation. Low thermal shrinkage, i.e., excellent dimensional stability. .精品课件. * Twaron（PPTA） Products Twaron is available as: Filament yarn, Staple fiber, Short fiber, Powder, Pulp, Fabrics and laminates Main applications Twaron is used to reinforce: Ignition cables, Communication cables, Heat-protection products, Cut-protection products, Ballistic-protection products, T