基多孔碳吸附典型环境污染物的.docxVIP

MOF-5基多孔碳吸附典型环境污染物的研究Adsorption MOF-5基多孔碳吸附典型环境污染物的研究 Adsorption of Typical Environmental Pollutants on MOF--5--derived Nanoporous Carbon Abstract Nanoporous carbon materials wim m曲specific surface area and excellent electrochemical performance have gained more and more attention．and have been widely applied in the fields of gas storage，catalyst support and SO on．Nanoporous carbon materials obtained by conventional methods usually got a higll surface area but had unttmable and random pore structures，which limited their applications．Therefore，the preparation of the nanoporous carbon with superior performance would greatly advance their applications．It has been demonstrated that MOF-derived carbon possesses not only regular and well．defined channel systems but also much higher surface area,which indicates that they may have a huge application potential in the adsorption field．However,to the best of our knowledge，no reports have been found about the adsorption properties of nanoporous carbon derived from MOFs。So this work investigated the adsorption performance of the MOF．．5．．derived nanoporous carbon(NPC)towards typical environmental pollutants(using sulfamethoxazole (SMX)，bisphenol A(BPA)and methyl orange(MO)as target pollutants)，and explored the influence of solution properties．The work iS expected to provide experimental foundation and theoretical basis for water treatment that NPC involves in．Correspondingly．several studies were conducted as follows： (1)By using MOF-5(Zn40(BDC)3)as precursor,NPC Was obtained by the method of direct carbonization，and the carbonization temperature of 1 000 oC Was maintained for 8 h． The physical—chemical characterization showed that N．PC possessed a surface area of nearly 2000 m2／g。and a pore volume higher than 2 cm’／g． (2)The adsorption performance of NPC towards SMX，BPA and M0 were investigated， compared with that of single．walled carbon nanotubes(SWNT)and powder active carbon (PAC)．It Was found that the adsorption kinetics of NPC