第四章多组分系统热力学.pptVIP

解：（1）?U1 ＝ 0，?H1 ＝ 0 Q1 = -W1 = nRTln(p1/p2) = -2691.4 J ?S1 ＝ Q/T = -7.62 J·K-1 (2) ?H2 ＝ Q2 = -30878 J W2 = nRT = 2937.3 J ?U2 = ?H2 +nRT = -27940.7 J ?S2 = ?H2/T = -87.41J·K-1 (3) ?H3 ＝ Q3 = -2868.27 J W3 = 0 ?U3 = ?H3 ?S3 = nCp,mln(T2/T1) = -8.36 J·K-1 总过程：Q = -36.437 kJ; W = 5.628 kJ, ?U = -30.8