超聲空化加紫外光助Fenton试剂处理RDX炸药废水研究.pdfVIP

中北大学学位论文 Study for Treatment of RDX Wastewater with Study for Treatment of RDX Wastewater with SSttuuddyy ffoorr TTrreeaattmmeenntt ooff RRDDXX WWaasstteewwaatteerr wwiitthh Ultrasonic Cavitation/ Ultraviolet/Fenton Technology Ultrasonic Cavitation/ Ultraviolet/Fenton Technology UUllttrraassoonniicc CCaavviittaattiioonn// UUllttrraavviioolleett//FFeennttoonn TTeecchhnnoollooggyy Abstract The treatment of the explosive wastewater is very important, the treatment of the the RDX in wastewater is particularly important. The wastewater treatment for the RDX wastewater has achieved some success in recent years. However, the RDX contains nitro, which has dangerous, biological toxicity and chemical stability, and which can easily lead to other more toxic intermediates in the degradation process, which makes it very difficult to degrade.The RDX wastewater was degraded with ultraviolet (UV)-Fenton, ultrasonic cavitation (US)-Fenton, ultrasonic cavitation plus UV-Fenton atnormal temperature.The effect toremoval rate of the RDX and CODcr of wastewater of reaction time the dosage of H O the dosage of FeSO ·7H O 、 2 2 、 4 2 、 pH and initial RDX concentration were investigated, and the optimum condition was determined via orthogonal and factor experiments.The results show that the synergistic effect of US/UV-Fenton is better than simply under the conditions of ultraviolet irradiation, or a simple ultrasonic cavitation treatment effect on the RDX; 2+ but also reduces dosage of H O and Fe , maintaining hydrogen peroxide and 2 2 ferrousions higher utilization, lower processing cost.The optimum conditions for dealing with RDX as follows: The optimum conditions for dealing with RDX as f