无机化学双语教学参考资料(下册)英文版.pdfVIP

无机化学双语教学 参考资料 ( 下册 ) 1 Chapter One Nitrogen Family (Group Ⅴ) Central contents: 1. Know the general properties of elements of the nitrogen group and inert electron pair effect 2. Know the reactions of ammonia, understand the thermal decomposition trend of ammonium salts 3. Know the properties of nitrous acid and nitrites; understand the structure of nitric acid and nitrate radical; understand the thermal decomposition trend of nitrates 4. Know well the properties of phosphoric acid and phosphates 5. Know the properties of oxides of As, Sb, Bi and their hydrates; understand the properties of sulfides of As, Sb, Bi; know the trends of these compounds 6. Understand the properties of the salts of As, Sb, Bi + - - 3- 3+ 4 2 3 4 7. Understand the identification methods for NH , NO , NO , PO and Bi 2 Section One The General Properties of Elements of the Nitrogen Group 1. Know the following: 2 3 1) Valence shell configuration nsnp 2) Nonmetal → metalloid → metal 3) Oxidation number: 0、+3、+5 4) Bonding character 2. Inert electron pair effect: In the same group, the stability will increase from up to down when the elements have lower oxidation number; but the stability will decrease from up to down when the elements have higher oxidation number 3 Section Two Nitro