地球化学：高等微量元素地球化学 第五章 岩浆作用中微量元素行为.ppt

* * * * * * D = 1.0 No fractionation so CL/CO = 1 for all values of F * Values of F 0.4 unlikely for batch melting since greater amounts should separate and rise * Highly incompatible elements are greatly concentrated in the initial small fraction of melt that is produced by partial melting, and subsequently get diluted as F increases * All - 1.0 because all of the source is melted * If know (CL) for magma derived by a small degree of batch melting, and we know D, we can estimate the concentration of that element in the source region (CO). This can provide very valuable information in constraining and characterizing the source region. * * * Results: Incompatible element Rb (no K minerals) strongly concentrated in the early small melt proportions (low F) Thus ? a sensitive measure of the progress of fractional crystallization (at least until rock half melted) As melting proceeds, the incompatible element is gradually diluted by more compatible ones Since D(Sr) is close to 1.0, the ratio Rb/Sr vs. F is nearly the same as Rb alone Any ratio of incompatible to compatible element should then be sensitive to the degree of partial melting (at least in the initial stages). Important for Rb/Sr isotopic systems Note that can create a series of melts from a single source each with diff Rb/Sr * * 部分熔融过程模拟 Rb Sr La Sc 熔融残留相 熔融残留相 Pla 0.071 1.830 0.010 0.070 Gar 0.042 0.012 0.001 4.000 0.15 0.30 Amp 0.290 0.460 0.544 4.200 0.50 0.35 Cpx 0.031 0.060 0.056 2.700 0.35 0.35 Opx 0.022 0.040 0.030 0.120 Oli 0.010 0.014 0.007 0.170 部分熔融源岩浓度 79 471 17 18 岩石分配系数（D1) 0.162 0.253 0.292 3.645 岩石分配系数（D2) 0.106 0.173 0.193 2.247 微量元素定量模拟曲线 F CRb=79 CSr=471 CSc=18 Cla=17 0.05 973 4415 0.007 142 0.10 544 2630 0.041 87 0.15 387 1943 0.120 65 0.20 304 1567 0.256 53 0.25 252 1327 0.462 45 0.30 217 1158 0.748 40 0.35 190 1032 1.124 36 0.40 170 934 1.599 33 0.45 154 855 2.183 30 0.50 141 790 2.884 28