介孔TiO,2纳米粉体制备 掺杂改性及其光催化性能研究.pdfVIP

Preparation，Doped Modification and Photocatalytic Properties ’of Mesoporous Tie2 Nano—Powder Abstract Mesoporous Ti02 materials have great application values in wastewater treatment and air purification because of its high photocatalytic properties．However, Mesoporous Tie2 photocatalyst has lower quantum yield and lower visible—light utilization ratio．To this problem，in this paper，advantages and disadvantages of mesoporous Ti02 photocatalyst which was prepared by hydrolysis precipitation method and Sol-Gel method were compared．Mesoporous Tie2 photocatalyst was prepared by hydrolysis precipitation method anddoped．modification．Itputforward one·-element or two·-element dopedmodification method to improve theproperty of mesoporous Ti02 photoeatalyst with transition metal ions as doping agent or rare earth ions．The crystal phase，microstructure，photocatalytic properties of the prepared mesoporous Ti02 were characterized by X—ray diffraction(XRD)，N2 adsorption·desorption isotherm ，transmission electron mieroscopy(TEM) ， Ultraviolet—Visible absorption spectrum，infrared spectrum．The influences of doped other ions to microstructure and properti es of Mesoporous Ti02 were investigated．The photocatalytic properties of mesoporous Ti02 in the degradation of methyl orange solution were determined．The effect of different molar ratio of doped agent，heat treatment temperature and concentrations of Tie2 to properties of one-element or two-element doped mesoporous Ti02 were also studied ．The photoeatalytic properties of mesoporous Tie2 were improved．The effect of different doped elements was investigated in the one--element or two·-element doped system． The results showed that after heat treatment at 50012 temperature