Cd(Ⅱ)金属有机配位聚合物的设计合成、结构研究.docxVIP

— PAGE \* Arabic 1 — Cd(Ⅱ)金属有机配位聚合物的设计合成、结构研究 大学学院  毕业论文  Cd(Ⅱ)金属有机配位聚合物的设计合  成、结构研究Syntheses, Structures Studies of Cd (Ⅱ) metal organic Coordination Polymers  系别：化学与药学系  专业：应用化学  姓名：吴雪梅  学号 指导教师、职称：薛铭副教授  完成时间2014年4 月5 日  大学学院本科毕业论文开题报告   Cd(Ⅱ)金属有机配位聚合物的设计合  成、结构研究   Syntheses, Structures Studies of Cd (Ⅱ) metal organic Coordination Polymers  Abstract  In recent years, the research of metal-organic coordination polymers with intriguing variety of architectural features and potential applications in gas adsorption, catalysis, magestism, chiral recognition and separation, luminescence and biology, nonlinear optical, and so on, has becoming a focus of the coordination chemistry and crystal engineering. Metal - organic framework material, referred to as MOFs, coordination polymers generally refers to the Metal ions and small molecules ligand formed through the self-assembly process with cyclical network structure. Metal - organic framework material preparation process has an important impact on its structural properties such as pore common synthetic methods are: hydrothermal synthesis method, solvothermal synthesis method, synthesis ion thermal, mechanical synthesis method ultrasonic synthesis.  In this paper, we have been hydrothermally synthesized to obtain the metal MOFs materials. by using bisimidazole ligands 5-(4-tetrazolyl)-phenylisophthalic acid (TZPI) to coordinate with Cd II. And preparation of materials out of crystals by X-ray powder diffraction, thermal gravimetric analysis to characterize these characterizations.  Keywords: Coordination polymer; 5-(4-tetrazolyl)-phenylisophthalic acid (TZPI);  1, 1?-(1, 4-butanediyl) bis (benzimidazole); XRD; Thermal stability.  目录  1 绪论 (1)  1.1 金属-有机骨架晶体材料 (1)  1.1.1 金属-有机骨架材料的介绍 (1)  1.1.2 金属-有机骨架材料的发展状况 (1)  1.2 金属-有机配位聚合物的合成方法 (2)  1.2.1 水热反应 (2)  1.3 本课题的选题目的及意义 (3)  2 实验部分 (4)