软化学和绿色合成方法.pptVIP

1) Mix the oxalates of zinc and iron together in water in a 1:1 ratio. Heat to evaporate off the water, as the amount of H2O decreases a mixed Zn/Fe acetate (probably hydrated) precipitates out. Fe2((COO)2)3 + Zn(COO)2 → Fe2Zn((COO)2)5·xH2O 2) After most of the water is gone, filter off the precipitate and calcine it (1000°C). Fe2Zn((COO)2)5 → ZnFe2O4 + 4CO + 4CO2 Coprecipitation Synthesis of ZnFe2O4 1). Reactants of comparable water solubility cannot be found. 2). The precipitation rates of the reactants is markedly different. 3). Accurate stoichiometric ratios may not always be maintained.