镍钴锰三元层状正极材料.docxVIP

镍钴锰三元层状正极材料 镍钴锰三元层状正极材料 The University of Texas at 那么掺入多少合适呢？ (Journal of The JournalofThe Electrochemical Society, 152 9 A1714-A1718 2021 (Ni?1/3Mn1/3Co1/3)(OH)2 (Li1?zNiz)3a[(Ni1/3?z/0.97Mn1/3Co1/3)0.97Liz+0.03]3b(O2)6c help?indirectly?to?identify?the?lithium?content?limit?1???x?within?which?the?Li1?xNi1/3Mn1/3Co1/3O2cathode?is?chemicallyy or?structurallyy stable3.0‐ 3.0‐4.6?v 问题：为什么充电截止电压超过4.6?v?时其容量衰减变大？ 同样我们也要问为什么？ but?the oxygen?loss?occurs?at?a?much?lower lithium?content?0.35?in?the Li1?xNi1/3Mn1/3Co1/3O2system?0.505?in?the?Li1?xCoO2system 那么1‐x=0.35与充电截止电压(4.6v) 有什么样的关系呢？ chemical?instability?plays?a?critical?role?in?the?capacity?retention?and?in?controlling?the?practical?capacities?of?the?Li1?xNi1/3Mn1/3Co1/3O2system. a?qualitative?band?diagram?for?the?Li0.35Ni1/3Mn1/3Co1/3O2system type?LiMO2 O1‐type?MO2 O3‐type?LiMO2O1‐type?MO21?????x 1-x=0.35 Mn1/3Co1/3O2?δ(O1?type) 放电曲线dued?to?theh?oxygen‐deficientdfii nature?of?Ni1/3Mn1/3Co1/3O2??δ?sNi1/3Mn1/3Co1/3O2?δδ放电之后的XRD因此，这种不可逆相变会导致容量 Electrochemicallhil?andd?Solidlid‐State?Letters,?8?(8)?C102‐C105?(2021) 什么是Irreversible?Capacity?Loss?(IRC)? the?first?cycle is?the?higher?irreversible?capacity?loss?in?the?first?cycle?为什么？ 晶格参数差异不大，离子混杂程度相差也不大。 那么是什么因素导致这种材料具有较大的IRC呢？ 700℃600℃ 但煅烧温度引起的晶格参数不同和离子混杂程度不是导致IRC差异的主要因素那么煅烧温度引起的什么因素导致这种IRC的差异呢？ LiNi1/3 Mn1/3Co1/3O2 3.0‐4.6v 3.0‐4.3vLiCoO23.0‐4.6v无离子混杂 问题：为什么表面积越大，IRC值越大呢？ the?parasitic?electrochemical?reactions?such?as?the?oxidation?of?the?electrolyte?occurring?on?the?cathode?surface?may?contribute?to?the?IRC?of?LiNi1/3Mn1/3Co1/3O2and?LiCoO2cathodes The?anodic?peak?at?around4.5?V?in?the?first?cyclebecomes?more?prominent?with?decreasing?synthesis?temperature?and?disappears?almost?completely?for?the?second?cycle.?This?observation?suggests?that?IRC?is?related?to?the?anodic?peak?at?4.5?V. LiNi1/2 Mn