电子顺磁共振(ESR)教程.pptVIP

MS=±? Electron S (?) Nucleus I (?) Selection Rule DMS = ±1 (electron) DMI = 0 (nuclear) B “doublet” a Hyperfine Coupling E = gbBSz + (hA0)SzIz E = gbBSz + (a)SzIz (hA0 (Hz) - a (G) via g-factor) +? -? -? +? MI DE1 = gbB + a/2 DE2 = gbB - a/2 DE1 – DE2 = a DE1 DE2 -? +? Ms 第二十六页，编辑于星期五：二十三点 五十四分。 ElectronParamagneticResonance, ElectronSpinResonance 第一页，编辑于星期五：二十三点 五十四分。 Energy Ms ±? B = 0 Magnetic Field (B) DBpp 磁诱导电子自旋能级裂分 Ms = +? Ms = -? h Planck’s constant 6.626196 x 10-27 erg.sec n frequency (GHz or MHz) g g-factor (approximately 2.0) b Bohr magneton (9.2741 x 10-21 erg.Gauss-1) B ma